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Here, the energy of the input photon is ampli ed thousands of times in the process Complicated biochemical pathways then revert the trans isomer back to cis and set the system backup for another cascade upon subsequent absorption Although we are yet unable to reconstruct the biological photoresponsive systems as they are, it is worthwhile mimicking their processes From the viewpoint of reversibility, speed, and simplicity of incorporation, perhaps azobenzene chromophores are the best photosensitive molecules to do this arti cial mimic Trans and cis states can be switched in picoseconds even with low power light, reversibility of 105 and 106 cycles is routine before fatigue, and a wide variety of molecular architectures is available to the synthetic materials chemist, permitting facile anchoring and compatibility, as well as chemical and physical ampli cation of the simple geometric change (Ikeda, 2003; Natansohn and Rochon, 2002).

function:

Therefore, this chapter describes various photodeformable polymer systems containing azobenzenes such as polymer gels, solid lms, and liquid crystals (LCs), focusing attention on light-responsive LC elastomers (LCEs) that are recently developed photomechanical systems Other photodeformable polymer systems such as colloidal particles and monolayers for which good reviews are included in the following chapters are skipped here By using their deformations, we can convert light energy into mechanical power directly (photomechanical effects) These systems have obvious attractiveness in basic science and are potential for many applications, for example, serving as arti cial muscles, sensors, microrobots, micropumps, and actuators..

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The most extensive investigations on SPs have been carried out on the polymer gels in which a network of long polymer molecules holds the liquid in place and so gives the gel what solidity it has Chemically cross-linked gels can undergo a transition between a collapsed and an expanded state, that is, between a shrunk and a swollen state (Fig 31) The difference between these two states could reach several orders of magnitude This behavior has been very attractive for the applications of the gels as potential actuators, sensors, controllable membranes for separations, and modulators for drug delivery (Osada and Gong, 1998) Studies on the light-responsive gels began as early as the 1970s Van der Veen and Prins (1971) prepared a gel system consisting of a low-molecular-weight (LMW) chrysophenine dye (1) and a water-swollen gel of poly(2-hydroxyethyl methacrylate) cross-linked with ethylene glycol dimethylacylate.

add_shortcode('textftw', 'text_example');

The polymer gel was found to contract upon irradiation of UV light, because the trans cis isomerization causes a reduction in hydrophobicity of the dye, librating the dyes from the polymer chain to the surrounding solution The same type of the photoinduced deformations was also observed in cross-linked poly(methacrylic acid) on which chrysophenine was absorbed (Van der Veen and Prins, 1974) In contrast, adsorption of the positively charged dye, 4-phenylazophenyl trimethylammonium iodide (2), to the cross-linked poly(methacrylic acid) lm led to the reverse of the photoresponsive behavior described earlier (Van der Veen et al, 1974) Swelling occurred upon irradiation of UV light, whereas contraction took place during relaxation in the dark The aqueous polymeric acid gel combined with the positively charged trans form takes on a more hydrophobic and globular conformation.

Saddened and unsurprised watching the prices change on Michael Jackson CDs in second hand shops. And sad about something else: Who da thunk that today would be the day that Michael Jackson died It feels fake. I m SO sad about Farrah Fawcett. Such a surreal day . . . And: TMZ.com claims that Michael Jackson is dead, but his Wikipedia page has yet to be updated. How sad is it that I went to Wikipedia Not to mention spam: RT @bowlsey @JamieC: Very sad about Michael Jackson. HABITAT for all your furniture needs habitat.co.uk. The red- ashing-light clue is right up front in the Key Findings section where they say, Roughly 3 of tweets about 4 Jackson s death that use the word sad actually express sadness, suggesting that sentiment analysis based on word usage is fairly accurate. In other words, using a brute-force bag-of-words approach to determining sentiment is wrong 25 percent of the time and this is considered fairly accurate. Yes it gets better. None of the people rating the tweets found any to be mixed and yet: All six raters agreed on only 235 (67.92 percent) tweets.

This creates the [textftw] shortcode, and loads it with the contents of the text_example() function. So [textftw] in your blog post will output in your post, Why, this text was just output using the shortcode tag you created! Smashing.

After irradiation of UV light, the more soluble cis isomer is formed, causing the dye to drop off the polymer As a result, the polymer relaxes to an extended conformation, and the sample swells..

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